Tag Archives: Thermal imaging

Thermal imaging as a universal indicator of chemical reactions: An example of acid-base titration

Fig. 1: NaOH-HCl titration
Funded by the National Science Foundation and in collaboration with Prof. Dunwei Wang's lab at the Department of Chemistry, Boston College, we are exploring the feasibility of using thermal imaging as a universal indicator of chemical reactions. The central tenet is that, as all chemical reactions absorb or release thermal energy (endothermic or exothermic), we can infer certain information from the time evolution and spatial distribution of the temperature field.

To prove the concept, we first chose titration, a common laboratory method of quantitative chemical analysis that is used to determine the unknown concentration of an identified analyte, as a beginning example. A reagent, called the titrant, is prepared as a standard solution. A known concentration and volume of titrant reacts with a solution of analyte to determine its concentration.

The experiment we did today was an acid-base titration. An acid–base titration is the determination of the concentration of an acid or base by exactly neutralizing the acid or base with a base or acid of known concentration. Such a titration is typically done with a burette that drops titrant into an Erlenmeyer flask containing the analyte. A pH indicator is used to determine whether the equivalence point has been reached. The pH indicator usually depends on the analyte and the titrant. But a differential thermal analysis based on infrared imaging may provide a universal indicator as the technique depends only on the heat of reaction and thermal energy is universal.

Fig. 2: The dish-array titration revealed by FLIR ONE
Figures 1 and 2 in this article show the results of the NaOH+HCl titration, taken using a FLIR ONE thermal camera attached to my iPhone 6. A solution of 10% NaOH was prepared as the analyte of "unknown" concentration and 1%, 3%, 5%, 7%, 10%, 12%, 15%, 18%, and 20% HCl were used as the titrant. The experiment was conducted with a 3×3 array of Petri dishes. Hence, we call this setup as dish-array titration. Preliminary results of this first experiment appeared to be encouraging, but we have to be cautious as the dissolving of HCl after the acid-base neutralization completes can also release a significant amount of heat. How to separate the thermal signatures of reaction and dissolving requires some further thinking.

A demo of Infrared Street View

An infrared street view
The award-winning Infrared Street View program is an ambitious project that aims to create something similar to Google's Street View, but in infrared light. The ultimate goal is to develop the world's first thermographic information system (TIS) that allows the positioning of thermal elements and the tracking of thermal processes on a massive scale. The applications include building energy efficiency, real estate inspection, and public security monitoring, to name a few.
An infrared image sphere

The Infrared Street View project is based on infrared cameras that work with now ubiquitous smartphones. It takes advantages of the orientation and location sensors of smartphones to store information necessary to knit an array of infrared thermal images taken at different angles and positions into a 3D image that, when rendered on a dome, creates an illusion of immersive 3D effects for the viewer.

The project was launched in 2016 and later joined by three brilliant computer science undergraduate students, Seth Kahn, Feiyu Lu, and Gabriel Terrell, from Tufts University, who developed a primitive system consisting of 1) an iOS frontend app to collect infrared image spheres, 2) a backend cloud app to process the images, and 3) a Web interface for users to view the stitched infrared images anchored at selected locations on a Google Maps application.

The following YouTube video demonstrates an early concept played out on an iPhone:

National Science Foundation funds chemical imaging research based on infrared thermography

The National Science Foundation (NSF) has awarded Bowling Green State University (BGSU) and Concord Consortium (CC) an exploratory grant of $300 K to investigate how chemical imaging based on infrared (IR) thermography can be used in chemistry labs to support undergraduate learning and teaching.

Chemists often rely on visually striking color changes shown by pH, redox, and other indicators to detect or track chemical changes. About six years ago, I realized that IR imaging may represent a novel class of universal indicators that, instead of using  halochromic compounds, use false color heat maps to visualize any chemical process that involves the absorption, release, or distribution of thermal energy (see my original paper published in 2011). I felt that IR thermography could one day become a powerful imaging technique for studying chemistry and biology. As the technique doesn't involve the use of any chemical substance as a detector, it could be considered as a "green" indicator.

Fig. 1: IR-based differential thermal analysis of freezing point depression
Although IR cameras are not new, inexpensive lightweight models have become available only recently. The releases of two competitively priced IR cameras for smartphones in 2014 marked an epoch of personal thermal vision. In January 2014, FLIR Systems unveiled the $349 FLIR ONE, the first camera that can be attached to an iPhone. Months later, a startup company Seek Thermal released a $199 IR camera that has an even higher resolution and can be connected to most smartphones. The race was on to make better and cheaper cameras. In January 2015, FLIR announced the second-generation FLIR ONE camera, priced at $231 in Amazon. With an educational discount, the price of an IR cameras is now comparable to what a single sensor may cost (e.g., Vernier sells an IR thermometer at $179). All these new cameras can take IR images just like taking conventional photos and record IR videos just like recording conventional videos. The manufacturers also provide application programming interfaces (APIs) for developers to blend thermal vision and computer vision in a smartphone to create interesting apps.

Fig. 2: IR-based differential thermal analysis of enzyme kinetics
Not surprisingly, many educators, including ourselves, have realized the value of IR cameras for teaching topics such as thermal radiation and heat transfer that are naturally supported by IR imaging. Applications in other fields such as chemistry, however, seem less obvious and remain underexplored, even though almost every chemistry reaction or phase transition absorbs or releases heat. The NSF project will focus on showing how IR imaging can become an extraordinary tool for chemical education. The project aims to develop seven curriculum units based on the use of IR imaging to support, accelerate, and expand inquiry-based learning for a wide range of chemistry concepts. The units will employ the predict-observe-explain (POE) cycle to scaffold inquiry in laboratory activities based on IR imaging. To demonstrate the versatility and generality of this approach, the units will cover a range of topics, such as thermodynamics, heat transfer, phase change, colligative properties (Figure 1), and enzyme kinetics (Figure 2).

The research will focus on finding robust evidence of learning due to IR imaging, with the goal to identify underlying cognitive mechanisms and recommend effective strategies for using IR imaging in chemistry education. This study will be conducted for a diverse student population at BGSU, Boston College, Bradley University, Owens Community College, Parkland College, St. John Fisher College, and SUNY Geneseo.

Partial support for this work was provided by the National Science Foundation's Improving Undergraduate STEM Education (IUSE) program under Award No. 1626228. Any opinions, findings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily reflect the views of the National Science Foundation.